flag flag  

author = "Neudörfl, Jörg M."
1

Found 9 documents, displaying page 1 of 1

Potassium (1-methoxy­carbonyl-2-methyl­prop-2-en-2-yl­idene)azinate

Description : In the title compound, K+·C6H8NO4 −, the K+ cations have a coordination number of seven and are surrounded by four bidentate azinate anions. The methyl­ene groups of the anions are always directed towards the coordinated potassium cations. The N—C—C—C torsion angle is 101.2 (2)°. The ...
Repository : Europe PubMed Central
Language(s) : English

Lithium phosphonate umpolung catalysts: Do fluoro substituents increase the catalytic activity?

Description : Fluorinated and nonfluorinated phosphonates are employed as precatalysts in lithium phosphonate catalyzed cross benzoin couplings. Surprisingly, a decreased catalytic activity for the fluorinated precatalysts compared to the nonfluorinated systems is observed. Furthermore, the ring size of six, seve...
Repository : Europe PubMed Central
Language(s) : English

Metal-mediated aminocatalysis provides mild conditions: Enantioselective Michael addition mediated by primary amino catalysts and alkali-metal ions

Description : Four catalysts based on new amides of chiral 1,2-diamines and 2-sulfobenzoic acid have been developed. The alkali-metal salts of these betaine-like amides are able to form imines with enones, which are activated by Lewis acid interaction for nucleophilic attack by 4-hydroxycoumarin. The addition of ...
Repository : Europe PubMed Central
Language(s) : English

Synthesis of spiroannulated and 3-arylated 1,2,4-trioxanes from mesitylol and methyl 4-hydroxytiglate by photooxygenation and peroxyacetalization

Description : Cycloalkanones were utilized in the Lewis acid catalyzed peroxyacetalization of ß-hydroperoxy homoallylic alcohols (prepared by the ene reaction of the allylic alcohols mesitylol and methyl 4-hydroxytiglate, respectively, with singlet oxygen) to give spiroannulated 1,2,4-trioxanes 5a–5e and 9a–9e, r...
Repository : Europe PubMed Central
Language(s) : English

(RS)-Tricarbon­yl(η4-1,3-diacet­oxy-5,5-dimethyl­cyclo­hexa-1,3-diene)iron(0)

Description : In the title compound, [Fe(C12H16O4)(CO)3], the diene moiety of the mol­ecule is virtually planar, with a C—C—C—C torsion angle of −1.4 (2)°. The six-membered ring exhibits a boat conformation, with torsion angles of 46.2 (2) and 46.5 (3)° for a double-bond and the two attached Csp 3 ...
Repository : Europe PubMed Central
Language(s) : English

Tris[(6S)-6-hy­droxy-4-epi-shikimic acid] monohydrate: an enanti­omerically pure hy­droxy­lated shikimic acid derived from methyl shikimate

Description : The title compound, 3C7H10O6·H2O, is the enanti­omerically pure product of a multi-step synthesis from the enanti­omerically pure natural shikimic acid. The asymmetric unit contains three mol­ecules of the acid and one mol­ecule of water. The cyclo­hexene rings of the acids have half-chair conformat...
Repository : Europe PubMed Central
Language(s) : English

trans-1,2-Bis(3,5-dimethoxy­phen­yl)ethene

Description : The title compound, C18H20O4, was prepared in high yield from 3,5-dimethoxy­styrene via a Ru-catalysed homo-olefin metathesis. Exclusive formation of the E-configurated isomer was observed. Inter­estingly, one symmetric unit contains two mol­ecules adopting an s-syn-anti and and an all-s-anti confor...
Repository : Europe PubMed Central
Language(s) : English

trans-Ethyl­enedi-p-phenyl­ene diacetate

Description : The centrosymmetric title compound, C18H26O4, was prepared in high yield from 4-acetoxy­styrene via Ru-catalysed homo-olefin metathesis. Exclusive formation of the E-configurated isomer was observed. In the crystal, a strong C—H⋯π inter­molecular inter­action links the mol­ecules together.
Repository : Europe PubMed Central
Language(s) : English

3β-Acet­oxy-19-hy­droxy-Δ5-pregnen-20-one

Description : In the title compound, C23H34O4, the C/D and D/E rings are trans fused and the A/B ring possesses an anti fusion. The two cyclo­hexane rings adopt a chair conformation while the cyclo­hexene ring exhibits a half-chair conformation. The cyclo­pentane ring displays an envelope conformation with the C ...
Repository : Europe PubMed Central
Language(s) : English
1

Found 9 documents, displaying page 1 of 1