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author = "LONGHI, GIOVANNA"
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Found 3 documents, displaying page 1 of 1

Chiroptical properties of some monoazapentahelicenes

Description : Three closely related previously synthesized monoaza[5]helicenes have been resolved into their enantiomers via enantioselective HPLC using a cellulose-derivative Chiralcel OD column. Circular dichroism (CD) spectra of the enantiomerically enriched samples have been recorded and assigned. The spectra...
Repository : Aisberg - Archivio Istituzionale Università di Bergamo
Language(s) : English

Experimental and calculated circular dichroism spectra of monoaza[5]helicenes

Description : Circular dichroism (CD) spectra have been measured in the range of 400–200 nm on CH3OH solutions of both enantiomers for the almost complete series of monoaza[5]helicenes, namely the molecules where the hetero N atom occupies positions 1, 3, 4, 5, 6, and 7, respectively (the 2 isomer is missing due ...
Repository : Aisberg - Archivio Istituzionale Università di Bergamo
Language(s) : English

2,13-diaza[5]helicene: synthesis, theoretical calculations and spectroscopic properties

Description : An easy approach to the synthesis of azahelicenes is based on the photochemical cyclisation of symmetrically or asymmetrically 1,2-aryl-substituted double bonds. In the synthesis of 2,13-diaza[5]helicene, irradiation of 9-(2-pyrid-4-yl-vinyl)-benzo[h]isoquinoline yielded 2,9-diaza-dibenzo[a.h]anthra...
Repository : Aisberg - Archivio Istituzionale Università di Bergamo
Language(s) : English
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Found 3 documents, displaying page 1 of 1